Iodine Monochloride Cas 7790 99 0 - Indiaprice: contact company for price
is a red-brown compound that melts near room temperature. Because of the
difference in the electronegativity of iodine and chlorine, ICl is
highly polar and behaves as a source of I+. Owing to the similarity of
the properties of the compound with bromine (red-brown liquid at room
temperature), its synthesis led early researchers to believe that the
reaction between the heaviest and lightest of a 'triad' of elements
(three elements with similar chemical properties, now found in the same
group of the modern periodic table) would produce the central element of
the triad, the so-named 'Law of Averages'.
Iodine monochloride is produced simply by combining the halogens in a 1:1 molar ratio, according to the equation
I2 + Cl2 → 2 ICl
When chlorine gas is passed through iodine crystals, one observes the brown vapor of iodine monochloride. Dark brown iodine monochloride liquid is collected. Excess chlorine converts iodine monochloride into iodine trichloride in a reversible reaction:
ICl + Cl2 is in equilibrium withICl3
ICl is a useful reagent in organic synthesis. It is used as a source of electrophilic iodine in the synthesis of certain aromatic iodides. It also cleaves C-Si bonds.
ICl will also add to the double bond in alkenes to give chloro-iodo alkanes.
RCH=CHR’ + ICl → RCH(I)-CH(Cl)R’
When such reactions are conducted in the presence of sodium azide, the iodo-azide RCH(I)-CH(N3)R’ is obtained.
This solution, which is iodine monochloride dissolved in acetic acid, is used to determine the iodine value of a substance.
Molecular formula : ClI
- Posted By: Infinium Pharmachem Pvt Ltd.
- Phone: 02692238850
- Address: Vallabh Vidyanagar, Anand, Vallabh Vidyanagar, Anand, India
- Website: http://www.sodiumiodide.net
Published date: November 15, 2013 -
- Business Description: At Infinium Pharmachem Pvt. Ltd., we are well focused to Iodine
chemistry & this is the only core area of ours. Hence, we are working as
CRAMS, but our domain is very restricted to Iodine chemistry & it
revolves around Iodine derivatives or Iodination. It is also reflected
in our Product List. We manufacture & supply range of Iodine
derivatives, but on Order to Made basis only. However, we keep in ready
stock many of well demanded products.
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